They were walking down the street around 5 a.m. this morning at Woods Avenue and Columbia Street when police said they got into an argument and she fired at the man, hitting a nearby business.
The business alarm picked up sounds of gunfire and glass breaking.
Both were taken into custody, police said. The woman was charged with attempted murder with a firearm, possession of a firearm by a convicted felon and resisting without violence.
The business experienced minor damage.
No one was hurt.